quantum-espresso/PHonon/examples/example16/reference/graphite.vdw-df.scf.out

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Program PWSCF v.6.4.1 starts on 20Sep2019 at 16: 9: 7
This program is part of the open-source Quantum ESPRESSO suite
for quantum simulation of materials; please cite
"P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
"P. Giannozzi et al., J. Phys.:Condens. Matter 29 465901 (2017);
URL http://www.quantum-espresso.org",
in publications or presentations arising from this work. More details at
http://www.quantum-espresso.org/quote
Parallel version (MPI), running on 4 processors
MPI processes distributed on 1 nodes
R & G space division: proc/nbgrp/npool/nimage = 4
Waiting for input...
Reading input from standard input
Current dimensions of program PWSCF are:
Max number of different atomic species (ntypx) = 10
Max number of k-points (npk) = 40000
Max angular momentum in pseudopotentials (lmaxx) = 3
IMPORTANT: XC functional enforced from input :
Exchange-correlation= VDW-DF
( 1 4 4 0 1 0 0)
Any further DFT definition will be discarded
Please, verify this is what you really want
file C.pbe-rrkjus.UPF: wavefunction(s) 2S 2P renormalized
Subspace diagonalization in iterative solution of the eigenvalue problem:
a serial algorithm will be used
Parallelization info
--------------------
sticks: dense smooth PW G-vecs: dense smooth PW
Min 65 46 15 2276 1235 259
Max 67 47 16 2279 1237 264
Sum 265 187 61 9111 4943 1045
bravais-lattice index = 4
lattice parameter (alat) = 4.6463 a.u.
unit-cell volume = 224.3370 (a.u.)^3
number of atoms/cell = 4
number of atomic types = 1
number of electrons = 16.00
number of Kohn-Sham states= 8
kinetic-energy cutoff = 30.0000 Ry
charge density cutoff = 180.0000 Ry
convergence threshold = 1.0E-12
mixing beta = 0.7000
number of iterations used = 8 plain mixing
Exchange-correlation= VDW-DF
( 1 4 4 0 1 0 0)
celldm(1)= 4.646303 celldm(2)= 0.000000 celldm(3)= 2.582543
celldm(4)= 0.000000 celldm(5)= 0.000000 celldm(6)= 0.000000
crystal axes: (cart. coord. in units of alat)
a(1) = ( 1.000000 0.000000 0.000000 )
a(2) = ( -0.500000 0.866025 0.000000 )
a(3) = ( 0.000000 0.000000 2.582543 )
reciprocal axes: (cart. coord. in units 2 pi/alat)
b(1) = ( 1.000000 0.577350 0.000000 )
b(2) = ( 0.000000 1.154701 0.000000 )
b(3) = ( 0.000000 0.000000 0.387215 )
PseudoPot. # 1 for C read from file:
/benchmarks/pseudo/C.pbe-rrkjus.UPF
MD5 check sum: c9ac5a99bc85b198593446162950cd17
Pseudo is Ultrasoft, Zval = 4.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 627 points, 4 beta functions with:
l(1) = 0
l(2) = 0
l(3) = 1
l(4) = 1
Q(r) pseudized with 0 coefficients
atomic species valence mass pseudopotential
C 4.00 12.00000 C ( 1.00)
24 Sym. Ops., with inversion, found (12 have fractional translation)
Cartesian axes
site n. atom positions (alat units)
1 C tau( 1) = ( 0.0000000 0.0000000 0.0000000 )
2 C tau( 2) = ( -0.0000000 0.5773503 0.0000000 )
3 C tau( 3) = ( 0.0000000 0.0000000 1.2912714 )
4 C tau( 4) = ( 0.5000000 0.2886751 1.2912714 )
number of k points= 6
cart. coord. in units 2pi/alat
k( 1) = ( 0.1250000 0.2165064 0.0968038), wk = 0.2500000
k( 2) = ( 0.1250000 0.5051815 0.0968038), wk = 0.5000000
k( 3) = ( 0.1250000 -0.3608439 0.0968038), wk = 0.5000000
k( 4) = ( 0.1250000 -0.0721688 0.0968038), wk = 0.2500000
k( 5) = ( 0.3750000 0.6495191 0.0968038), wk = 0.2500000
k( 6) = ( 0.3750000 -0.2165064 0.0968038), wk = 0.2500000
Dense grid: 9111 G-vectors FFT dimensions: ( 20, 20, 54)
Smooth grid: 4943 G-vectors FFT dimensions: ( 18, 18, 48)
Estimated max dynamical RAM per process > 3.39 MB
Estimated total dynamical RAM > 13.58 MB
Initial potential from superposition of free atoms
starting charge 15.99979, renormalised to 16.00000
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
% %
% You are using vdW-DF, which was implemented by the Thonhauser group. %
% Please cite the following two papers that made this development %
% possible and the two reviews that describe the various versions: %
% %
% T. Thonhauser et al., PRL 115, 136402 (2015). %
% T. Thonhauser et al., PRB 76, 125112 (2007). %
% K. Berland et al., Rep. Prog. Phys. 78, 066501 (2015). %
% D.C. Langreth et al., J. Phys.: Condens. Matter 21, 084203 (2009). %
% %
% %
% If you are calculating the stress with vdW-DF, please also cite: %
% %
% R. Sabatini et al., J. Phys.: Condens. Matter 24, 424209 (2012). %
% %
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
Starting wfcs are 16 randomized atomic wfcs
total cpu time spent up to now is 25.4 secs
Self-consistent Calculation
iteration # 1 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.00E-02, avg # of iterations = 2.0
total cpu time spent up to now is 25.4 secs
total energy = -45.81537064 Ry
Harris-Foulkes estimate = -46.05259572 Ry
estimated scf accuracy < 0.42906803 Ry
iteration # 2 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 2.68E-03, avg # of iterations = 2.0
total cpu time spent up to now is 25.5 secs
total energy = -45.87729814 Ry
Harris-Foulkes estimate = -45.87595856 Ry
estimated scf accuracy < 0.00525176 Ry
iteration # 3 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 3.28E-05, avg # of iterations = 2.5
total cpu time spent up to now is 25.5 secs
total energy = -45.87812971 Ry
Harris-Foulkes estimate = -45.87794212 Ry
estimated scf accuracy < 0.00039868 Ry
iteration # 4 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 2.49E-06, avg # of iterations = 1.5
total cpu time spent up to now is 25.5 secs
total energy = -45.87816598 Ry
Harris-Foulkes estimate = -45.87816437 Ry
estimated scf accuracy < 0.00000423 Ry
iteration # 5 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 2.64E-08, avg # of iterations = 3.5
total cpu time spent up to now is 25.6 secs
total energy = -45.87816949 Ry
Harris-Foulkes estimate = -45.87816934 Ry
estimated scf accuracy < 0.00000034 Ry
iteration # 6 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 2.14E-09, avg # of iterations = 3.3
total cpu time spent up to now is 25.6 secs
total energy = -45.87816953 Ry
Harris-Foulkes estimate = -45.87816960 Ry
estimated scf accuracy < 0.00000013 Ry
iteration # 7 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 8.30E-10, avg # of iterations = 2.7
total cpu time spent up to now is 25.7 secs
total energy = -45.87816956 Ry
Harris-Foulkes estimate = -45.87816957 Ry
estimated scf accuracy < 0.00000003 Ry
iteration # 8 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.76E-10, avg # of iterations = 2.7
total cpu time spent up to now is 25.7 secs
total energy = -45.87816957 Ry
Harris-Foulkes estimate = -45.87816957 Ry
estimated scf accuracy < 1.8E-10 Ry
iteration # 9 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.10E-12, avg # of iterations = 3.8
total cpu time spent up to now is 25.8 secs
total energy = -45.87816957 Ry
Harris-Foulkes estimate = -45.87816957 Ry
estimated scf accuracy < 1.1E-10 Ry
iteration # 10 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 6.67E-13, avg # of iterations = 2.7
total cpu time spent up to now is 25.8 secs
total energy = -45.87816957 Ry
Harris-Foulkes estimate = -45.87816957 Ry
estimated scf accuracy < 3.1E-12 Ry
iteration # 11 ecut= 30.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.00E-13, avg # of iterations = 1.8
total cpu time spent up to now is 25.9 secs
End of self-consistent calculation
k = 0.1250 0.2165 0.0968 ( 619 PWs) bands (ev):
-10.9292 -10.6363 0.5597 1.2917 1.3409 2.2425 2.3780 2.4123
k = 0.1250 0.5052 0.0968 ( 628 PWs) bands (ev):
-7.4066 -7.1849 -4.4847 -4.3166 0.0918 0.1800 4.5348 5.6329
k = 0.1250-0.3608 0.0968 ( 627 PWs) bands (ev):
-9.4801 -9.2135 -1.4960 -1.3776 0.8616 0.9353 2.2769 3.8186
k = 0.1250-0.0722 0.0968 ( 606 PWs) bands (ev):
-11.6656 -11.3594 -0.3285 1.4093 3.0718 3.1253 3.7433 3.7832
k = 0.3750 0.6495 0.0968 ( 630 PWs) bands (ev):
-5.8014 -5.6911 -4.8560 -4.8135 -2.1716 -2.0649 6.2356 6.8601
k = 0.3750-0.2165 0.0968 ( 623 PWs) bands (ev):
-8.7696 -8.5164 -3.1851 -3.0257 1.4468 1.5077 3.0669 4.4844
highest occupied level (ev): 6.8601
! total energy = -45.87816957 Ry
Harris-Foulkes estimate = -45.87816957 Ry
estimated scf accuracy < 8.5E-13 Ry
The total energy is the sum of the following terms:
one-electron contribution = -7.16846936 Ry
hartree contribution = 11.99235762 Ry
xc contribution = -14.43288043 Ry
ewald contribution = -36.26917740 Ry
convergence has been achieved in 11 iterations
Writing output data file /benchmarks/tempdir/graphite.save/
init_run : 25.23s CPU 25.25s WALL ( 1 calls)
electrons : 0.42s CPU 0.49s WALL ( 1 calls)
Called by init_run:
wfcinit : 0.01s CPU 0.02s WALL ( 1 calls)
potinit : 25.20s CPU 25.21s WALL ( 1 calls)
hinit0 : 0.01s CPU 0.01s WALL ( 1 calls)
Called by electrons:
c_bands : 0.21s CPU 0.24s WALL ( 11 calls)
sum_band : 0.05s CPU 0.06s WALL ( 11 calls)
v_of_rho : 25.33s CPU 25.37s WALL ( 12 calls)
newd : 0.01s CPU 0.02s WALL ( 12 calls)
mix_rho : 0.01s CPU 0.01s WALL ( 11 calls)
vdW_kernel : 25.18s CPU 25.19s WALL ( 1 calls)
Called by c_bands:
init_us_2 : 0.00s CPU 0.01s WALL ( 138 calls)
cegterg : 0.20s CPU 0.22s WALL ( 66 calls)
Called by sum_band:
sum_band:bec : 0.00s CPU 0.00s WALL ( 66 calls)
addusdens : 0.01s CPU 0.01s WALL ( 11 calls)
Called by *egterg:
h_psi : 0.15s CPU 0.17s WALL ( 243 calls)
s_psi : 0.01s CPU 0.01s WALL ( 243 calls)
g_psi : 0.00s CPU 0.00s WALL ( 171 calls)
cdiaghg : 0.03s CPU 0.03s WALL ( 237 calls)
Called by h_psi:
h_psi:calbec : 0.01s CPU 0.01s WALL ( 243 calls)
vloc_psi : 0.13s CPU 0.14s WALL ( 243 calls)
add_vuspsi : 0.01s CPU 0.01s WALL ( 243 calls)
General routines
calbec : 0.01s CPU 0.01s WALL ( 309 calls)
fft : 0.08s CPU 0.08s WALL ( 753 calls)
ffts : 0.00s CPU 0.00s WALL ( 23 calls)
fftw : 0.14s CPU 0.15s WALL ( 3744 calls)
interpolate : 0.00s CPU 0.00s WALL ( 12 calls)
Parallel routines
fft_scatt_xy : 0.03s CPU 0.03s WALL ( 4520 calls)
fft_scatt_yz : 0.08s CPU 0.09s WALL ( 4520 calls)
PWSCF : 25.76s CPU 25.93s WALL
This run was terminated on: 16: 9:33 20Sep2019
=------------------------------------------------------------------------------=
JOB DONE.
=------------------------------------------------------------------------------=