quantum-espresso/test-suite/pw_workflow_exx_nscf/benchmark.out.git.inp=uspp-...

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Program PWSCF v.7.0 starts on 10Jan2022 at 15:41:41
This program is part of the open-source Quantum ESPRESSO suite
for quantum simulation of materials; please cite
"P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
"P. Giannozzi et al., J. Phys.:Condens. Matter 29 465901 (2017);
"P. Giannozzi et al., J. Chem. Phys. 152 154105 (2020);
URL http://www.quantum-espresso.org",
in publications or presentations arising from this work. More details at
http://www.quantum-espresso.org/quote
Parallel version (MPI), running on 1 processors
MPI processes distributed on 1 nodes
13454 MiB available memory on the printing compute node when the environment starts
Reading input from uspp-gamma-scf.in
Current dimensions of program PWSCF are:
Max number of different atomic species (ntypx) = 10
Max number of k-points (npk) = 40000
Max angular momentum in pseudopotentials (lmaxx) = 4
file H.pbe-rrkjus.UPF: wavefunction(s) 1S renormalized
file C.pbe-rrkjus.UPF: wavefunction(s) 2S 2P renormalized
IMPORTANT: XC functional enforced from input :
Exchange-correlation= PBE0
( 6 4 8 4 0 0 0)
EXX-fraction = 0.25
Any further DFT definition will be discarded
Please, verify this is what you really want
gamma-point specific algorithms are used
EXX: q-point mesh: 1 1 1
EXX: grid of k+q points same as grid of k-points
Subspace diagonalization in iterative solution of the eigenvalue problem:
a serial algorithm will be used
G-vector sticks info
--------------------
sticks: dense smooth PW G-vecs: dense smooth PW
Sum 405 405 101 6187 6187 751
Using Slab Decomposition
bravais-lattice index = 1
lattice parameter (alat) = 8.0000 a.u.
unit-cell volume = 512.0000 (a.u.)^3
number of atoms/cell = 10
number of atomic types = 2
number of electrons = 22.00
number of Kohn-Sham states= 11
kinetic-energy cutoff = 20.0000 Ry
charge density cutoff = 80.0000 Ry
cutoff for Fock operator = 80.0000 Ry
scf convergence threshold = 1.0E-06
mixing beta = 0.7000
number of iterations used = 8 plain mixing
Exchange-correlation= PBE0
( 6 4 8 4 0 0 0)
EXX-fraction = 0.25
celldm(1)= 8.000000 celldm(2)= 0.000000 celldm(3)= 0.000000
celldm(4)= 0.000000 celldm(5)= 0.000000 celldm(6)= 0.000000
crystal axes: (cart. coord. in units of alat)
a(1) = ( 1.000000 0.000000 0.000000 )
a(2) = ( 0.000000 1.000000 0.000000 )
a(3) = ( 0.000000 0.000000 1.000000 )
reciprocal axes: (cart. coord. in units 2 pi/alat)
b(1) = ( 1.000000 0.000000 0.000000 )
b(2) = ( 0.000000 1.000000 0.000000 )
b(3) = ( 0.000000 0.000000 1.000000 )
PseudoPot. # 1 for H read from file:
/home/ivan/devel/q-e-exx/test-suite/..//pseudo/H.pbe-rrkjus.UPF
MD5 check sum: 2d52a7f45632fd764c17cc6affed14c8
Pseudo is Ultrasoft, Zval = 1.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 1061 points, 2 beta functions with:
l(1) = 0
l(2) = 0
Q(r) pseudized with 0 coefficients
PseudoPot. # 2 for C read from file:
/home/ivan/devel/q-e-exx/test-suite/..//pseudo/C.pbe-rrkjus.UPF
MD5 check sum: c9ac5a99bc85b198593446162950cd17
Pseudo is Ultrasoft, Zval = 4.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 627 points, 4 beta functions with:
l(1) = 0
l(2) = 0
l(3) = 1
l(4) = 1
Q(r) pseudized with 0 coefficients
atomic species valence mass pseudopotential
H 1.00 1.00783 H ( 1.00)
C 4.00 12.00000 C ( 1.00)
No symmetry found
Cartesian axes
site n. atom positions (alat units)
1 H tau( 1) = ( -0.3396188 -0.3072775 0.2952175 )
2 H tau( 2) = ( -0.3641150 0.3114112 0.1191170 )
3 H tau( 3) = ( 0.2545363 -0.3380175 -0.1311087 )
4 H tau( 4) = ( 0.3886387 -0.2037337 0.2366638 )
5 H tau( 5) = ( 0.3060188 0.3298075 0.0415838 )
6 H tau( 6) = ( 0.1176044 0.2002337 -0.3229712 )
7 C tau( 7) = ( -0.1518812 -0.1636275 0.1645763 )
8 C tau( 8) = ( -0.1701575 0.1457675 0.1031486 )
9 C tau( 9) = ( 0.1935900 -0.1791975 0.0638284 )
10 C tau( 10) = ( 0.1368550 0.1713513 -0.0621193 )
number of k points= 1
cart. coord. in units 2pi/alat
k( 1) = ( 0.0000000 0.0000000 0.0000000), wk = 2.0000000
Dense grid: 3094 G-vectors FFT dimensions: ( 24, 24, 24)
Estimated max dynamical RAM per process > 7.24 MB
EXX: ACE will be initialized later
Initial potential from superposition of free atoms
starting charge 21.4226, renormalised to 22.0000
Starting wfcs are 22 randomized atomic wfcs
total cpu time spent up to now is 0.2 secs
Self-consistent Calculation
iteration # 1 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.00E-02, avg # of iterations = 2.0
total cpu time spent up to now is 0.2 secs
total energy = -52.20484895 Ry
estimated scf accuracy < 1.36632313 Ry
iteration # 2 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 6.21E-03, avg # of iterations = 2.0
total cpu time spent up to now is 0.2 secs
total energy = -52.36192615 Ry
estimated scf accuracy < 0.09792825 Ry
iteration # 3 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 4.45E-04, avg # of iterations = 2.0
total cpu time spent up to now is 0.2 secs
total energy = -52.37956384 Ry
estimated scf accuracy < 0.01099805 Ry
iteration # 4 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 5.00E-05, avg # of iterations = 2.0
total cpu time spent up to now is 0.2 secs
total energy = -52.38168364 Ry
estimated scf accuracy < 0.00019609 Ry
iteration # 5 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 8.91E-07, avg # of iterations = 3.0
total cpu time spent up to now is 0.2 secs
total energy = -52.38171319 Ry
estimated scf accuracy < 0.00004234 Ry
iteration # 6 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.92E-07, avg # of iterations = 3.0
total cpu time spent up to now is 0.3 secs
total energy = -52.38172385 Ry
estimated scf accuracy < 0.00001278 Ry
iteration # 7 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 5.81E-08, avg # of iterations = 3.0
total cpu time spent up to now is 0.3 secs
End of self-consistent calculation
k = 0.0000 0.0000 0.0000 ( 376 PWs) bands (ev):
-15.4527 -9.5254 -9.0704 -7.9073 -4.7148 -4.0593 -3.6291 -2.6584
-1.5302 -1.2569 0.2961
highest occupied level (ev): 0.2961
! total energy = -52.38172547 Ry
estimated scf accuracy < 0.00000070 Ry
convergence has been achieved in 7 iterations
Using ACE for calculation of exact exchange
EXX grid: 3094 G-vectors FFT dimensions: ( 24, 24, 24)
ACE projected onto 11 (nbndproj) and applied to 11 (nbnd) bands
EXX: now go back to refine exchange calculation
total cpu time spent up to now is 0.8 secs
Self-consistent Calculation
iteration # 1 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 5.81E-08, avg # of iterations = 7.0
negative rho (up, down): 1.032E-06 0.000E+00
total cpu time spent up to now is 0.8 secs
total energy = -52.53055784 Ry
estimated scf accuracy < 0.00069793 Ry
iteration # 2 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 3.17E-06, avg # of iterations = 4.0
negative rho (up, down): 5.995E-07 0.000E+00
total cpu time spent up to now is 0.8 secs
total energy = -52.41271882 Ry
estimated scf accuracy < 0.00267867 Ry
iteration # 3 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 3.17E-06, avg # of iterations = 2.0
negative rho (up, down): 2.086E-07 0.000E+00
total cpu time spent up to now is 0.8 secs
total energy = -52.41250197 Ry
estimated scf accuracy < 0.00092436 Ry
iteration # 4 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 3.17E-06, avg # of iterations = 1.0
total cpu time spent up to now is 0.8 secs
total energy = -52.41239324 Ry
estimated scf accuracy < 0.00025098 Ry
iteration # 5 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.14E-06, avg # of iterations = 2.0
total cpu time spent up to now is 0.8 secs
total energy = -52.41244640 Ry
estimated scf accuracy < 0.00000343 Ry
iteration # 6 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.56E-08, avg # of iterations = 2.0
total cpu time spent up to now is 0.8 secs
End of self-consistent calculation
k = 0.0000 0.0000 0.0000 ( 376 PWs) bands (ev):
-18.3715 -11.8950 -11.3747 -9.8379 -6.5468 -5.7676 -5.2684 -4.2917
-3.0590 -2.7537 -1.0089
highest occupied level (ev): -1.0089
! total energy = -52.41244693 Ry
estimated scf accuracy < 0.00000008 Ry
convergence has been achieved in 6 iterations
Using ACE for calculation of exact exchange
ACE projected onto 11 (nbndproj) and applied to 11 (nbnd) bands
total energy = -52.41277105 Ry
Harris-Foulkes estimate = -52.41277110 Ry
est. exchange err (dexx) = 0.00032412 Ry
- averaged Fock potential = 8.42452644 Ry
+ Fock energy (ACE) = -4.21322123 Ry
EXX: now go back to refine exchange calculation
total cpu time spent up to now is 1.3 secs
Self-consistent Calculation
iteration # 1 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.56E-08, avg # of iterations = 5.0
total cpu time spent up to now is 1.3 secs
total energy = -52.41281159 Ry
estimated scf accuracy < 0.00000685 Ry
iteration # 2 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 3.11E-08, avg # of iterations = 2.0
total cpu time spent up to now is 1.3 secs
End of self-consistent calculation
k = 0.0000 0.0000 0.0000 ( 376 PWs) bands (ev):
-18.3804 -11.9024 -11.3814 -9.8409 -6.5513 -5.7701 -5.2744 -4.2969
-3.0648 -2.7601 -1.0130
highest occupied level (ev): -1.0130
! total energy = -52.41281239 Ry
estimated scf accuracy < 0.00000080 Ry
convergence has been achieved in 2 iterations
Using ACE for calculation of exact exchange
ACE projected onto 11 (nbndproj) and applied to 11 (nbnd) bands
total energy = -52.41281980 Ry
Harris-Foulkes estimate = -52.41282038 Ry
est. exchange err (dexx) = 0.00000741 Ry
- averaged Fock potential = 8.42706864 Ry
+ Fock energy (ACE) = -4.21385482 Ry
EXX: now go back to refine exchange calculation
total cpu time spent up to now is 1.8 secs
Self-consistent Calculation
iteration # 1 ecut= 20.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 3.11E-08, avg # of iterations = 3.0
total cpu time spent up to now is 1.8 secs
End of self-consistent calculation
k = 0.0000 0.0000 0.0000 ( 376 PWs) bands (ev):
-18.3740 -11.8991 -11.3784 -9.8382 -6.5502 -5.7673 -5.2699 -4.2947
-3.0615 -2.7570 -1.0091
highest occupied level (ev): -1.0091
! total energy = -52.41282124 Ry
estimated scf accuracy < 0.00000095 Ry
convergence has been achieved in 1 iterations
Using ACE for calculation of exact exchange
ACE projected onto 11 (nbndproj) and applied to 11 (nbnd) bands
!! total energy = -52.41282182 Ry
Harris-Foulkes estimate = -52.41282260 Ry
est. exchange err (dexx) = 0.00000057 Ry
- averaged Fock potential = 8.42764760 Ry
+ Fock energy (ACE) = -4.21379335 Ry
EXX self-consistency reached
Writing all to output data dir ./pwscf.save/
init_run : 0.12s CPU 0.12s WALL ( 1 calls)
electrons : 0.25s CPU 0.26s WALL ( 4 calls)
Called by init_run:
aceinit0 : 0.00s CPU 0.00s WALL ( 1 calls)
wfcinit : 0.00s CPU 0.00s WALL ( 1 calls)
potinit : 0.01s CPU 0.01s WALL ( 1 calls)
hinit0 : 0.10s CPU 0.10s WALL ( 1 calls)
Called by electrons:
c_bands : 0.06s CPU 0.06s WALL ( 16 calls)
sum_band : 0.04s CPU 0.05s WALL ( 16 calls)
v_of_rho : 0.12s CPU 0.12s WALL ( 18 calls)
newd : 0.04s CPU 0.04s WALL ( 17 calls)
mix_rho : 0.00s CPU 0.00s WALL ( 16 calls)
Called by c_bands:
init_us_2 : 0.01s CPU 0.01s WALL ( 81 calls)
init_us_2:cp : 0.01s CPU 0.01s WALL ( 81 calls)
regterg : 0.05s CPU 0.05s WALL ( 16 calls)
Called by *egterg:
rdiaghg : 0.01s CPU 0.01s WALL ( 58 calls)
h_psi : 0.04s CPU 0.04s WALL ( 62 calls)
s_psi : 0.00s CPU 0.00s WALL ( 62 calls)
g_psi : 0.00s CPU 0.00s WALL ( 45 calls)
Called by h_psi:
h_psi:calbec : 0.00s CPU 0.00s WALL ( 62 calls)
vloc_psi : 0.03s CPU 0.03s WALL ( 62 calls)
add_vuspsi : 0.00s CPU 0.00s WALL ( 62 calls)
General routines
calbec : 0.00s CPU 0.00s WALL ( 137 calls)
fft : 0.01s CPU 0.01s WALL ( 155 calls)
ffts : 0.00s CPU 0.00s WALL ( 16 calls)
fftw : 0.02s CPU 0.03s WALL ( 750 calls)
fftc : 0.03s CPU 0.03s WALL ( 528 calls)
fftcw : 0.00s CPU 0.01s WALL ( 92 calls)
Parallel routines
EXX routines
exx_grid : 0.00s CPU 0.00s WALL ( 1 calls)
exxinit : 0.00s CPU 0.01s WALL ( 4 calls)
vexx : 1.80s CPU 1.83s WALL ( 4 calls)
matcalc : 0.00s CPU 0.00s WALL ( 55 calls)
aceupdate : 0.00s CPU 0.00s WALL ( 4 calls)
vexxace : 0.00s CPU 0.00s WALL ( 44 calls)
aceinit : 1.80s CPU 1.83s WALL ( 4 calls)
EXX+US routines
becxx : 0.00s CPU 0.00s WALL ( 4 calls)
addusxx : 0.84s CPU 0.85s WALL ( 484 calls)
newdxx : 0.82s CPU 0.83s WALL ( 484 calls)
qvan_init : 0.00s CPU 0.01s WALL ( 4 calls)
nlxx_pot : 0.00s CPU 0.01s WALL ( 44 calls)
PWSCF : 2.23s CPU 2.29s WALL
This run was terminated on: 15:41:44 10Jan2022
=------------------------------------------------------------------------------=
JOB DONE.
=------------------------------------------------------------------------------=