quantum-espresso/PW/examples/ESM_example/run_example_ESM

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#!/bin/sh
###############################################################################
##
## ESM EXAMPLE
##
###############################################################################
EXAMPLE_DIR=`pwd`
# check whether echo has the -e option
if test "`echo -e`" = "-e" ; then ECHO=echo ; else ECHO="echo -e" ; fi
$ECHO
$ECHO "run_example_ESM : starting"
$ECHO
$ECHO "This example shows how to use ESM to calculate H2O and Al(001)"
$ECHO "using the three available sets of boundary conditions."
$ECHO
# set the needed environment variables
. ../../../environment_variables
# required executables and pseudopotentials
BIN_LIST="pw.x"
PSEUDO_LIST="Al.pbe-n-van.UPF H.pbe-van_ak.UPF O.pbe-van_ak.UPF"
$ECHO
$ECHO " executables directory: $BIN_DIR"
$ECHO " pseudo directory: $PSEUDO_DIR"
$ECHO " temporary directory: $TMP_DIR"
$ECHO " checking that needed directories and files exist...\c"
# check for directories
for DIR in "$BIN_DIR" "$PSEUDO_DIR" ; do
if test ! -d $DIR ; then
$ECHO
$ECHO "ERROR: $DIR not existent or not a directory"
$ECHO "Aborting"
exit 1
fi
done
for DIR in "$TMP_DIR" "$EXAMPLE_DIR/results" ; do
if test ! -d $DIR ; then
mkdir $DIR
fi
done
cd $EXAMPLE_DIR/results
# check for executables
for FILE in $BIN_LIST ; do
if test ! -x $BIN_DIR/$FILE ; then
$ECHO
$ECHO "ERROR: $BIN_DIR/$FILE not existent or not executable"
$ECHO "Aborting"
exit 1
fi
done
# check for pseudopotentials
for FILE in $PSEUDO_LIST ; do
if test ! -r $PSEUDO_DIR/$FILE ; then
$ECHO
$ECHO "Downloading $FILE to $PSEUDO_DIR...\c"
echo $WGET $PSEUDO_DIR/$FILE $NETWORK_PSEUDO/$FILE
$WGET $PSEUDO_DIR/$FILE $NETWORK_PSEUDO/$FILE 2> /dev/null
fi
if test $? != 0; then
$ECHO
$ECHO "ERROR: $PSEUDO_DIR/$FILE not existent or not readable"
$ECHO "Aborting"
exit 1
fi
done
$ECHO " done"
# how to run executables
PW_COMMAND="$PARA_PREFIX $BIN_DIR/pw.x $PARA_POSTFIX"
$ECHO
$ECHO " running pw.x as: $PW_COMMAND"
$ECHO
# scf calculation for H2O with no ESM
cat > H2O_pbc.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='H2O_pbc',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 3, ntyp= 2,
ecutwfc = 25.0, ecutrho = 200.0,
occupations='smearing', smearing='mp', degauss=0.03,
assume_isolated = 'esm', esm_bc='pbc'
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
H 1.00794 H.pbe-van_ak.UPF
O 55.847 O.pbe-van_ak.UPF
CELL_PARAMETERS angstrom
10.5835400000 0.0000000000 0.0000000000
0.0000000000 10.5835400000 0.0000000000
0.0000000000 0.0000000000 12.7002480000
ATOMIC_POSITIONS angstrom
O 0.0000000000 5.2917700000 0.0000000000
H 0.4565612154 4.5618084292 0.4559209112
H 0.3877322213 6.1004201907 0.3804697962
K_POINTS gamma
EOF
$ECHO " running the calculation for H2O without ESM...\c"
$PW_COMMAND < H2O_pbc.in > H2O_pbc.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/H2O_pbc.esm1 $TMP_DIR/H2O_pbc.xml .
# scf calculation for H2O with ESM bc1 (vacuum-slab-vacuum)
cat > H2O_bc1.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='H2O_bc1',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 3, ntyp= 2,
ecutwfc = 25.0, ecutrho = 200.0,
occupations='smearing', smearing='mp', degauss=0.03,
assume_isolated = 'esm', esm_bc='bc1'
/
&electrons
mixing_beta = 0.3
/
ATOMIC_SPECIES
H 1.00794 H.pbe-van_ak.UPF
O 55.847 O.pbe-van_ak.UPF
CELL_PARAMETERS angstrom
10.5835400000 0.0000000000 0.0000000000
0.0000000000 10.5835400000 0.0000000000
0.0000000000 0.0000000000 12.7002480000
ATOMIC_POSITIONS angstrom
O 0.0000000000 5.2917700000 0.0000000000
H 0.4565612154 4.5618084292 0.4559209112
H 0.3877322213 6.1004201907 0.3804697962
K_POINTS gamma
EOF
$ECHO " running the calculation for H2O with ESM bc1 (vacuum-slab-vacuum)...\c"
$PW_COMMAND < H2O_bc1.in > H2O_bc1.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/H2O_bc1.esm1 $TMP_DIR/H2O_bc1.xml .
# clean TMP_DIR
$ECHO " cleaning $TMP_DIR...\c"
rm -rf $TMP_DIR/H2O*
$ECHO " done"
# calculation for Al(001) without ESM
cat > Al001_pbc.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_pbc',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='pbc'
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) without ESM\c"
$PW_COMMAND < Al001_pbc.in > Al001_pbc.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_pbc.esm1 $TMP_DIR/Al001_pbc.xml .
# calculation for Al(001) with ESM bc1 (vacuum-slab-vacuum)
cat > Al001_bc1.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_bc1',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='bc1'
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) with ESM bc1 (vacuum-slab-vacuuml)"
$PW_COMMAND < Al001_bc1.in > Al001_bc1.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_bc1.esm1 $TMP_DIR/Al001_bc1.xml .
# calculation for Al(001) with ESM bc2 (metal-slab-metal), no field
cat > Al001_bc2.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_bc2',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='bc2'
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) with ESM bc2 (metal-slab-metal)"
$ECHO " (no applied field)...\c"
$PW_COMMAND < Al001_bc2.in > Al001_bc2.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_bc2.esm1 $TMP_DIR/Al001_bc2.xml .
# calculation for Al(001) with ESM bc2 (metal-slab-metal), with field
cat > Al001_bc2_efield.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_bc2_efield',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='bc2', esm_efield=0.00192148511256006
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) with ESM bc2 (metal-slab-metal)"
$ECHO " with applied electric field...\c"
$PW_COMMAND < Al001_bc2_efield.in > Al001_bc2_efield.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_bc2_efield.esm1 $TMP_DIR/Al001_bc2_efield.xml .
# calculation for Al(001) with ESM bc3 (vacuum-slab-metal), uncharged
cat > Al001_bc3.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_bc3',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='bc3'
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) with ESM bc3 (vacuum-slab-metal)"
$ECHO " (neutrally charged)...\c"
$PW_COMMAND < Al001_bc3.in > Al001_bc3.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_bc3.esm1 $TMP_DIR/Al001_bc3.xml .
# calculation for Al(001) with ESM bc3 (vacuum-slab-metal), - charged
cat > Al001_bc3_m002.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_bc3_m002',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='bc3'
tot_charge = -0.02,
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) with ESM bc3 (vacuum-slab-metal)"
$ECHO " (-0.02e charged)...\c"
$PW_COMMAND < Al001_bc3_m002.in > Al001_bc3_m002.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_bc3_m002.esm1 $TMP_DIR/Al001_bc3_m002.xml .
# calculation for Al(001) with ESM bc3 (vacuum-slab-metal), + charged
cat > Al001_bc3_p002.in << EOF
&control
calculation='scf',
restart_mode='from_scratch',
prefix='Al001_bc3_p002',
pseudo_dir = '$PSEUDO_DIR/',
outdir='$TMP_DIR/',
tprnfor = .TRUE.
/
&system
ibrav = 0,
nat= 4, ntyp= 1,
ecutwfc = 20.0,
occupations='smearing', smearing='mp', degauss=0.03
assume_isolated='esm', esm_bc='bc3'
tot_charge = 0.02,
/
&electrons
diagonalization = 'rmm-davidson'
mixing_beta = 0.3
/
ATOMIC_SPECIES
Al 26.981538 Al.pbe-n-van.UPF
CELL_PARAMETERS angstrom
5.7269000760 0.0000000000 0.0000000000
0.0000000000 5.7269000760 0.0000000000
0.0000000000 0.0000000000 11.9999975199
ATOMIC_POSITIONS angstrom
Al 0.0000000000 0.0000000000 0.0000000000
Al 2.8634500380 0.0000000000 0.0000000000
Al 0.0000000000 2.8634500380 0.0000000000
Al 2.8634500380 2.8634500380 0.0000000000
K_POINTS automatic
6 6 1 1 1 0
EOF
$ECHO " running the calculation for Al(001) with ESM bc3 (vacuum-slab-metal)"
$ECHO " (+0.02e charged)...\c"
$PW_COMMAND < Al001_bc3_p002.in > Al001_bc3_p002.out
check_failure $?
$ECHO " done"
mv $TMP_DIR/Al001_bc3_p002.esm1 $TMP_DIR/Al001_bc3_p002.xml .
# clean TMP_DIR
$ECHO " cleaning $TMP_DIR...\c"
rm -rf $TMP_DIR/
$ECHO " done"
$ECHO
$ECHO "run_example_ESM: done"