quantum-espresso/test-suite/tddfpt_CH4/benchmark.out.git.inp=CH4.p...

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Program PWSCF v.7.3.1 starts on 9Apr2024 at 12:20:54
This program is part of the open-source Quantum ESPRESSO suite
for quantum simulation of materials; please cite
"P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
"P. Giannozzi et al., J. Phys.:Condens. Matter 29 465901 (2017);
"P. Giannozzi et al., J. Chem. Phys. 152 154105 (2020);
URL http://www.quantum-espresso.org",
in publications or presentations arising from this work. More details at
http://www.quantum-espresso.org/quote
Parallel version (MPI & OpenMP), running on 1 processor cores
Number of MPI processes: 1
Threads/MPI process: 1
MPI processes distributed on 1 nodes
498225 MiB available memory on the printing compute node when the environment starts
Waiting for input...
Reading input from standard input
Current dimensions of program PWSCF are:
Max number of different atomic species (ntypx) = 10
Max number of k-points (npk) = 40000
Max angular momentum in pseudopotentials (lmaxx) = 4
file H.pz-vbc.UPF: wavefunction(s) 1S renormalized
gamma-point specific algorithms are used
Subspace diagonalization in iterative solution of the eigenvalue problem:
a serial algorithm will be used
G-vector sticks info
--------------------
sticks: dense smooth PW G-vecs: dense smooth PW
Sum 7153 7153 1789 455863 455863 57051
Using Slab Decomposition
Title:
TDDFPT CH4 Test
bravais-lattice index = 1
lattice parameter (alat) = 30.0000 a.u.
unit-cell volume = 27000.0000 (a.u.)^3
number of atoms/cell = 5
number of atomic types = 2
number of electrons = 8.00
number of Kohn-Sham states= 4
kinetic-energy cutoff = 25.0000 Ry
charge density cutoff = 100.0000 Ry
scf convergence threshold = 1.0E-10
mixing beta = 0.7000
number of iterations used = 8 plain mixing
Exchange-correlation= SLA PZ NOGX NOGC
( 1 1 0 0 0 0 0)
GPU acceleration is ACTIVE. 4 visible GPUs per MPI rank
celldm(1)= 30.000000 celldm(2)= 0.000000 celldm(3)= 0.000000
celldm(4)= 0.000000 celldm(5)= 0.000000 celldm(6)= 0.000000
crystal axes: (cart. coord. in units of alat)
a(1) = ( 1.000000 0.000000 0.000000 )
a(2) = ( 0.000000 1.000000 0.000000 )
a(3) = ( 0.000000 0.000000 1.000000 )
reciprocal axes: (cart. coord. in units 2 pi/alat)
b(1) = ( 1.000000 0.000000 0.000000 )
b(2) = ( 0.000000 1.000000 0.000000 )
b(3) = ( 0.000000 0.000000 1.000000 )
PseudoPot. # 1 for C read from file:
/leonardo_scratch/large/userexternal/obaseggi/q-e-develop/test-suite/..//pseudo/C.pz-vbc.UPF
MD5 check sum: f697e42eaa1e52b77fcf7925dd36a1dd
Pseudo is Norm-conserving, Zval = 4.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 269 points, 1 beta functions with:
l(1) = 0
PseudoPot. # 2 for H read from file:
/leonardo_scratch/large/userexternal/obaseggi/q-e-develop/test-suite/..//pseudo/H.pz-vbc.UPF
MD5 check sum: b4742c37e165d3c4b97552e3cd66ffd5
Pseudo is Norm-conserving, Zval = 1.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 131 points, 0 beta functions with:
atomic species valence mass pseudopotential
C 4.00 1.00000 C ( 1.00)
H 1.00 1.00000 H ( 1.00)
24 Sym. Ops. (no inversion) found
Cartesian axes
site n. atom positions (alat units)
1 C tau( 1) = ( 0.0000000 0.0000000 0.0000000 )
2 H tau( 2) = ( 0.0404914 0.0404914 0.0404914 )
3 H tau( 3) = ( -0.0404914 -0.0404914 0.0404914 )
4 H tau( 4) = ( 0.0404914 -0.0404914 -0.0404914 )
5 H tau( 5) = ( -0.0404914 0.0404914 -0.0404914 )
number of k points= 1
cart. coord. in units 2pi/alat
k( 1) = ( 0.0000000 0.0000000 0.0000000), wk = 2.0000000
Dense grid: 227932 G-vectors FFT dimensions: ( 96, 96, 96)
Estimated max dynamical RAM per process > 171.63 MB
Initial potential from superposition of free atoms
starting charge 7.9999, renormalised to 8.0000
negative rho (up, down): 3.930E-02 0.000E+00
Starting wfcs are 8 atomic wfcs
total cpu time spent up to now is 2.9 secs
Self-consistent Calculation
iteration # 1 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.00E-02, avg # of iterations = 2.0
negative rho (up, down): 1.155E-02 0.000E+00
total cpu time spent up to now is 3.0 secs
total energy = -15.62232665 Ry
estimated scf accuracy < 0.54297404 Ry
iteration # 2 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 6.79E-03, avg # of iterations = 2.0
negative rho (up, down): 5.851E-03 0.000E+00
total cpu time spent up to now is 3.1 secs
total energy = -15.75507270 Ry
estimated scf accuracy < 0.14504194 Ry
iteration # 3 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.81E-03, avg # of iterations = 2.0
negative rho (up, down): 1.048E-04 0.000E+00
total cpu time spent up to now is 3.1 secs
total energy = -15.77626998 Ry
estimated scf accuracy < 0.00335641 Ry
iteration # 4 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 4.20E-05, avg # of iterations = 2.0
negative rho (up, down): 2.416E-04 0.000E+00
total cpu time spent up to now is 3.2 secs
total energy = -15.77710967 Ry
estimated scf accuracy < 0.00109836 Ry
iteration # 5 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.37E-05, avg # of iterations = 1.0
total cpu time spent up to now is 3.2 secs
total energy = -15.77709283 Ry
estimated scf accuracy < 0.00010345 Ry
iteration # 6 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.29E-06, avg # of iterations = 3.0
negative rho (up, down): 5.090E-07 0.000E+00
total cpu time spent up to now is 3.3 secs
total energy = -15.77706460 Ry
estimated scf accuracy < 0.00048653 Ry
iteration # 7 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.29E-06, avg # of iterations = 2.0
total cpu time spent up to now is 3.4 secs
total energy = -15.77714541 Ry
estimated scf accuracy < 0.00000083 Ry
iteration # 8 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.04E-08, avg # of iterations = 4.0
negative rho (up, down): 1.150E-08 0.000E+00
total cpu time spent up to now is 3.4 secs
total energy = -15.77714644 Ry
estimated scf accuracy < 0.00000464 Ry
iteration # 9 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 1.04E-08, avg # of iterations = 2.0
total cpu time spent up to now is 3.5 secs
total energy = -15.77714679 Ry
estimated scf accuracy < 0.00000021 Ry
iteration # 10 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 2.63E-09, avg # of iterations = 2.0
total cpu time spent up to now is 3.6 secs
total energy = -15.77714689 Ry
estimated scf accuracy < 0.00000004 Ry
iteration # 11 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 4.52E-10, avg # of iterations = 2.0
total cpu time spent up to now is 3.6 secs
total energy = -15.77714686 Ry
estimated scf accuracy < 0.00000007 Ry
iteration # 12 ecut= 25.00 Ry beta= 0.70
Davidson diagonalization with overlap
ethr = 4.52E-10, avg # of iterations = 2.0
total cpu time spent up to now is 3.7 secs
End of self-consistent calculation
k = 0.0000 0.0000 0.0000 ( 28526 PWs) bands (ev):
-16.9089 -9.3077 -9.3077 -9.3077
highest occupied level (ev): -9.3077
! total energy = -15.77714687 Ry
estimated scf accuracy < 5.8E-11 Ry
The total energy is the sum of the following terms:
one-electron contribution = -46.10026319 Ry
hartree contribution = 23.71658874 Ry
xc contribution = -6.06422088 Ry
ewald contribution = 12.67074846 Ry
convergence has been achieved in 12 iterations
Writing all to output data dir ./out/CH4.save/ :
XML data file, charge density, pseudopotentials, collected wavefunctions
init_run : 0.64s CPU 2.86s WALL ( 1 calls)
electrons : 0.64s CPU 0.73s WALL ( 1 calls)
Called by init_run:
wfcinit : 0.54s CPU 2.67s WALL ( 1 calls)
potinit : 0.02s CPU 0.03s WALL ( 1 calls)
hinit0 : 0.02s CPU 0.07s WALL ( 1 calls)
Called by electrons:
c_bands : 0.09s CPU 0.09s WALL ( 12 calls)
sum_band : 0.07s CPU 0.08s WALL ( 12 calls)
v_of_rho : 0.13s CPU 0.14s WALL ( 13 calls)
mix_rho : 0.27s CPU 0.32s WALL ( 12 calls)
Called by c_bands:
init_us_2 : 0.01s CPU 0.01s WALL ( 25 calls)
regterg : 0.07s CPU 0.07s WALL ( 12 calls)
Called by *egterg:
rdiaghg : 0.06s CPU 0.75s WALL ( 38 calls)
0.75s GPU ( 38 calls)
h_psi : 0.54s CPU 1.97s WALL ( 39 calls)
1.97s GPU ( 39 calls)
g_psi : 0.00s CPU 0.00s WALL ( 26 calls)
0.00s GPU ( 26 calls)
Called by h_psi:
h_psi:calbec : 0.49s CPU 1.93s WALL ( 39 calls)
1.93s GPU ( 39 calls)
vloc_psi : 0.03s CPU 0.03s WALL ( 39 calls)
0.03s GPU ( 39 calls)
add_vuspsi : 0.00s CPU 0.00s WALL ( 39 calls)
0.00s GPU ( 39 calls)
General routines
calbec : 0.49s CPU 1.92s WALL ( 39 calls)
fft : 0.01s CPU 0.04s WALL ( 38 calls)
0.04s GPU ( 38 calls)
ffts : 0.00s CPU 0.00s WALL ( 12 calls)
0.00s GPU ( 12 calls)
fftw : 0.00s CPU 0.02s WALL ( 102 calls)
0.02s GPU ( 102 calls)
Parallel routines
PWSCF : 1.31s CPU 3.70s WALL
This run was terminated on: 12:20:58 9Apr2024
=------------------------------------------------------------------------------=
JOB DONE.
=------------------------------------------------------------------------------=