quantum-espresso/PW/examples/ESM_example/reference/Al001_bc3_GCSCF_vp05.out

402 lines
16 KiB
Plaintext

Program PWSCF v.7.0rc1 starts on 1Dec2021 at 11:19:56
Git branch: dev-rism
Last git commit: 0f89c8bb5a130116d85338b1454d7fb3d9957a45
Last git commit date: Wed Dec 1 11:03:07 2021 +0900
Last git commit subject: update Doc/release-notes
This program is part of the open-source Quantum ESPRESSO suite
for quantum simulation of materials; please cite
"P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
"P. Giannozzi et al., J. Phys.:Condens. Matter 29 465901 (2017);
"P. Giannozzi et al., J. Chem. Phys. 152 154105 (2020);
URL http://www.quantum-espresso.org",
in publications or presentations arising from this work. More details at
http://www.quantum-espresso.org/quote
Parallel version (MPI), running on 4 processors
MPI processes distributed on 1 nodes
R & G space division: proc/nbgrp/npool/nimage = 4
0 MiB available memory on the printing compute node when the environment starts
Waiting for input...
Reading input from standard input
Current dimensions of program PWSCF are:
Max number of different atomic species (ntypx) = 10
Max number of k-points (npk) = 40000
Max angular momentum in pseudopotentials (lmaxx) = 4
Message from routine iosys:
mixing_mode=plain is ignored, 'TF' is adopted
Message from routine iosys:
accurate eigenvalues are required for all states: diago_full_acc=.TRUE.
Found identity + ( -0.5000 0.0000 0.0000) symmetry
This is a supercell, fractional translations are disabled
Message from routine setup:
using ibrav=0 with symmetry is DISCOURAGED, use correct ibrav instead
Subspace diagonalization in iterative solution of the eigenvalue problem:
a serial algorithm will be used
Parallelization info
--------------------
sticks: dense smooth PW G-vecs: dense smooth PW
Min 187 187 54 8037 8037 1261
Max 188 188 56 8044 8044 1262
Sum 749 749 221 32157 32157 5047
Using Slab Decomposition
bravais-lattice index = 0
lattice parameter (alat) = 10.8223 a.u.
unit-cell volume = 2655.9321 (a.u.)^3
number of atoms/cell = 4
number of atomic types = 1
number of electrons = 12.00
number of Kohn-Sham states= 10
kinetic-energy cutoff = 20.0000 Ry
charge density cutoff = 80.0000 Ry
scf convergence threshold = 1.0E-06
mixing beta = 0.3000
number of iterations used = 8 TF mixing
Exchange-correlation= SLA PW PBE PBE
( 1 4 3 4 0 0 0)
Effective Screening Medium Method
=================================
Boundary Conditions: Vacuum-Slab-Metal
total charge in unit cell = 0.0000
grid points for fit at edges = 4
>>>>> Grand-Canonical SCF is activated <<<<<
Initial Total Charge = 0.000000 e
Target Fermi Energy = -4.749000 eV
Thr. of Fermi Energy = 0.010000 eV
Wave-shift of Kerker = 0.400000 bohr^-1
Wave-shift of Hartree = 1.500000 bohr^-1
Mixing Rate of Fermi = 0.050000
celldm(1)= 10.822273 celldm(2)= 0.000000 celldm(3)= 0.000000
celldm(4)= 0.000000 celldm(5)= 0.000000 celldm(6)= 0.000000
crystal axes: (cart. coord. in units of alat)
a(1) = ( 1.000000 0.000000 0.000000 )
a(2) = ( 0.000000 1.000000 0.000000 )
a(3) = ( 0.000000 0.000000 2.095374 )
reciprocal axes: (cart. coord. in units 2 pi/alat)
b(1) = ( 1.000000 0.000000 0.000000 )
b(2) = ( 0.000000 1.000000 0.000000 )
b(3) = ( 0.000000 0.000000 0.477242 )
PseudoPot. # 1 for Al read from file:
/Users/otani/Program/q-e/git-worktrees/dev-rism/pseudo/Al.pbe-n-van.UPF
MD5 check sum: cbc97ad259b400557db688b98a6ada97
Pseudo is Ultrasoft + core correction, Zval = 3.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 893 points, 2 beta functions with:
l(1) = 0
l(2) = 1
Q(r) pseudized with 8 coefficients, rinner = 0.900 0.900 0.900
atomic species valence mass pseudopotential
Al 3.00 26.98154 Al( 1.00)
8 Sym. Ops. (no inversion) found
Cartesian axes
site n. atom positions (alat units)
1 Al tau( 1) = ( 0.0000000 0.0000000 0.0000000 )
2 Al tau( 2) = ( 0.5000000 0.0000000 0.0000000 )
3 Al tau( 3) = ( 0.0000000 0.5000000 0.0000000 )
4 Al tau( 4) = ( 0.5000000 0.5000000 0.0000000 )
number of k points= 6 Methfessel-Paxton smearing, width (Ry)= 0.0300
cart. coord. in units 2pi/alat
k( 1) = ( 0.0833333 0.0833333 0.0000000), wk = 0.2222222
k( 2) = ( 0.0833333 0.2500000 0.0000000), wk = 0.4444444
k( 3) = ( 0.0833333 0.4166667 0.0000000), wk = 0.4444444
k( 4) = ( 0.2500000 0.2500000 0.0000000), wk = 0.2222222
k( 5) = ( 0.2500000 0.4166667 0.0000000), wk = 0.4444444
k( 6) = ( 0.4166667 0.4166667 0.0000000), wk = 0.2222222
Dense grid: 32157 G-vectors FFT dimensions: ( 32, 32, 72)
Estimated max dynamical RAM per process > 9.36 MB
Estimated total dynamical RAM > 37.46 MB
Check: negative core charge= -0.000012
Initial potential from superposition of free atoms
starting charge 11.9901, renormalised to 12.0000
negative rho (up, down): 1.687E-04 0.000E+00
Starting wfcs are 16 randomized atomic wfcs
total cpu time spent up to now is 0.4 secs
Self-consistent Calculation
iteration # 1 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.00E-05, avg # of iterations = 37.5
negative rho (up, down): 9.025E-06 0.000E+00
total cpu time spent up to now is 1.1 secs
total energy = -49.53055127 Ry
estimated scf accuracy < 0.02327987 Ry
total charge of GC-SCF = -0.00482337 e
the Fermi energy = -5.16051601 eV
(error : 0.41151601 eV)
iteration # 2 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.00E-05, avg # of iterations = 3.5
total cpu time spent up to now is 1.2 secs
total energy = -49.50978206 Ry
estimated scf accuracy < 0.01295450 Ry
total charge of GC-SCF = -0.01106717 e
the Fermi energy = -4.88872530 eV
(error : 0.13972530 eV)
iteration # 3 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.00E-05, avg # of iterations = 8.5
total cpu time spent up to now is 1.4 secs
total energy = -49.51775361 Ry
estimated scf accuracy < 0.00028338 Ry
total charge of GC-SCF = -0.00050821 e
the Fermi energy = -4.28184450 eV
(error : 0.46715550 eV)
iteration # 4 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 2.36E-06, avg # of iterations = 6.7
total cpu time spent up to now is 1.5 secs
total energy = -49.51726745 Ry
estimated scf accuracy < 0.00015717 Ry
total charge of GC-SCF = 0.00524888 e
the Fermi energy = -4.60793195 eV
(error : 0.14106805 eV)
iteration # 5 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.31E-06, avg # of iterations = 5.8
total cpu time spent up to now is 1.6 secs
total energy = -49.51742929 Ry
estimated scf accuracy < 0.00004919 Ry
total charge of GC-SCF = 0.00878458 e
the Fermi energy = -4.66279379 eV
(error : 0.08620621 eV)
iteration # 6 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 4.10E-07, avg # of iterations = 9.2
total cpu time spent up to now is 1.7 secs
total energy = -49.51751063 Ry
estimated scf accuracy < 0.00000846 Ry
total charge of GC-SCF = 0.01084814 e
the Fermi energy = -4.63492492 eV
(error : 0.11407508 eV)
iteration # 7 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 7.05E-08, avg # of iterations = 12.7
total cpu time spent up to now is 1.9 secs
total energy = -49.51756818 Ry
estimated scf accuracy < 0.00000495 Ry
total charge of GC-SCF = 0.01395310 e
the Fermi energy = -4.68614690 eV
(error : 0.06285310 eV)
iteration # 8 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 4.13E-08, avg # of iterations = 9.7
total cpu time spent up to now is 2.1 secs
total energy = -49.51756536 Ry
estimated scf accuracy < 0.00000199 Ry
total charge of GC-SCF = 0.01606893 e
the Fermi energy = -4.67969843 eV
(error : 0.06930157 eV)
iteration # 9 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
c_bands: 1 eigenvalues not converged
ethr = 1.66E-08, avg # of iterations = 38.0
total cpu time spent up to now is 2.4 secs
total energy = -49.51741495 Ry
estimated scf accuracy < 0.00000051 Ry
total charge of GC-SCF = 0.01969804 e
the Fermi energy = -4.71104112 eV
(error : 0.03795888 eV)
iteration # 10 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
c_bands: 1 eigenvalues not converged
ethr = 4.27E-09, avg # of iterations = 41.5
total cpu time spent up to now is 2.7 secs
total energy = -49.51736146 Ry
estimated scf accuracy < 0.00000012 Ry
total charge of GC-SCF = 0.01996225 e
the Fermi energy = -4.73420997 eV
(error : 0.01479003 eV)
iteration # 11 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 9.73E-10, avg # of iterations = 32.3
total cpu time spent up to now is 3.0 secs
End of self-consistent calculation
k = 0.0833 0.0833 0.0000 ( 3999 PWs) bands (ev):
-11.8389 -8.2635 -8.2635 -6.5552 -6.5552 -5.7843 -4.7780 -3.9057
-2.6109 -2.5516
k = 0.0833 0.2500 0.0000 ( 4011 PWs) bands (ev):
-11.5908 -9.3961 -8.0193 -6.3275 -5.8768 -5.5468 -4.9838 -4.4239
-3.4805 -2.3209
k = 0.0833 0.4167 0.0000 ( 4016 PWs) bands (ev):
-11.0966 -10.3611 -7.5336 -6.8140 -5.8761 -5.2202 -5.0745 -4.3759
-3.1490 -1.8629
k = 0.2500 0.2500 0.0000 ( 4007 PWs) bands (ev):
-11.3430 -9.1517 -9.1517 -6.9972 -5.3095 -4.7618 -4.7618 -3.4491
-3.2466 -3.2466
k = 0.2500 0.4167 0.0000 ( 4019 PWs) bands (ev):
-10.8494 -10.1151 -8.6653 -7.9432 -4.8379 -4.3318 -4.1404 -3.7495
-2.9494 -2.7811
k = 0.4167 0.4167 0.0000 ( 4005 PWs) bands (ev):
-10.3574 -9.6257 -9.6257 -8.8977 -4.3671 -3.6715 -3.6715 -2.9785
-2.6016 -2.6016
the Fermi energy is -4.7393 ev
! total energy = -49.51710451 Ry
estimated scf accuracy < 0.00000012 Ry
! total charge of GC-SCF = 0.02177671 e
smearing contrib. (-TS) = -0.00029185 Ry
internal energy E=F+TS = -49.51681266 Ry
The total energy is F=E-TS. E is the sum of the following terms:
one-electron contribution = -319.73758974 Ry
hartree contribution = 160.20940635 Ry
xc contribution = -39.21314453 Ry
ewald contribution = 149.23211632 Ry
pot.stat. contrib. (-muN) = -0.00760105 Ry
convergence has been achieved in 11 iterations
Forces acting on atoms (cartesian axes, Ry/au):
atom 1 type 1 force = 0.00000000 0.00000000 -0.00000240
atom 2 type 1 force = 0.00000000 0.00000000 -0.00000158
atom 3 type 1 force = 0.00000000 0.00000000 -0.00000158
atom 4 type 1 force = 0.00000000 0.00000000 -0.00000124
Total force = 0.000004 Total SCF correction = 0.000544
SCF correction compared to forces is large: reduce conv_thr to get better values
Writing all to output data dir /Users/otani/Program/q-e/git-worktrees/dev-rism/tempdir/Al001_bc3_GCSCF_vp05.save/
init_run : 0.39s CPU 0.40s WALL ( 1 calls)
electrons : 2.51s CPU 2.57s WALL ( 1 calls)
forces : 0.05s CPU 0.05s WALL ( 1 calls)
Called by init_run:
wfcinit : 0.03s CPU 0.03s WALL ( 1 calls)
potinit : 0.02s CPU 0.03s WALL ( 1 calls)
hinit0 : 0.29s CPU 0.29s WALL ( 1 calls)
Called by electrons:
c_bands : 2.23s CPU 2.28s WALL ( 11 calls)
sum_band : 0.13s CPU 0.14s WALL ( 11 calls)
v_of_rho : 0.10s CPU 0.11s WALL ( 12 calls)
newd : 0.03s CPU 0.03s WALL ( 12 calls)
mix_rho : 0.02s CPU 0.02s WALL ( 11 calls)
Called by c_bands:
init_us_2 : 0.02s CPU 0.02s WALL ( 144 calls)
init_us_2:cp : 0.02s CPU 0.02s WALL ( 144 calls)
cegterg : 2.21s CPU 2.26s WALL ( 98 calls)
Called by *egterg:
cdiaghg : 0.14s CPU 0.14s WALL ( 1323 calls)
h_psi : 1.65s CPU 1.69s WALL ( 1336 calls)
s_psi : 0.04s CPU 0.04s WALL ( 1336 calls)
g_psi : 0.02s CPU 0.02s WALL ( 1232 calls)
Called by h_psi:
h_psi:calbec : 0.07s CPU 0.07s WALL ( 1336 calls)
vloc_psi : 1.51s CPU 1.54s WALL ( 1336 calls)
add_vuspsi : 0.06s CPU 0.06s WALL ( 1336 calls)
General routines
calbec : 0.08s CPU 0.08s WALL ( 1426 calls)
fft : 0.15s CPU 0.15s WALL ( 143 calls)
ffts : 0.00s CPU 0.00s WALL ( 11 calls)
fftw : 1.35s CPU 1.37s WALL ( 14224 calls)
Parallel routines
PWSCF : 2.97s CPU 3.07s WALL
This run was terminated on: 11:19:59 1Dec2021
=------------------------------------------------------------------------------=
JOB DONE.
=------------------------------------------------------------------------------=