quantum-espresso/PW/examples/ESM_example/reference/Al001_bc2_GCSCF_vp05.out

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Program PWSCF v.7.0rc1 starts on 1Dec2021 at 11:19:47
Git branch: dev-rism
Last git commit: 0f89c8bb5a130116d85338b1454d7fb3d9957a45
Last git commit date: Wed Dec 1 11:03:07 2021 +0900
Last git commit subject: update Doc/release-notes
This program is part of the open-source Quantum ESPRESSO suite
for quantum simulation of materials; please cite
"P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
"P. Giannozzi et al., J. Phys.:Condens. Matter 29 465901 (2017);
"P. Giannozzi et al., J. Chem. Phys. 152 154105 (2020);
URL http://www.quantum-espresso.org",
in publications or presentations arising from this work. More details at
http://www.quantum-espresso.org/quote
Parallel version (MPI), running on 4 processors
MPI processes distributed on 1 nodes
R & G space division: proc/nbgrp/npool/nimage = 4
0 MiB available memory on the printing compute node when the environment starts
Waiting for input...
Reading input from standard input
Current dimensions of program PWSCF are:
Max number of different atomic species (ntypx) = 10
Max number of k-points (npk) = 40000
Max angular momentum in pseudopotentials (lmaxx) = 4
Message from routine iosys:
mixing_mode=plain is ignored, 'TF' is adopted
Message from routine iosys:
accurate eigenvalues are required for all states: diago_full_acc=.TRUE.
Found identity + ( -0.5000 0.0000 0.0000) symmetry
This is a supercell, fractional translations are disabled
Message from routine setup:
using ibrav=0 with symmetry is DISCOURAGED, use correct ibrav instead
Subspace diagonalization in iterative solution of the eigenvalue problem:
a serial algorithm will be used
Parallelization info
--------------------
sticks: dense smooth PW G-vecs: dense smooth PW
Min 187 187 54 8037 8037 1261
Max 188 188 56 8044 8044 1262
Sum 749 749 221 32157 32157 5047
Using Slab Decomposition
bravais-lattice index = 0
lattice parameter (alat) = 10.8223 a.u.
unit-cell volume = 2655.9321 (a.u.)^3
number of atoms/cell = 4
number of atomic types = 1
number of electrons = 12.00
number of Kohn-Sham states= 10
kinetic-energy cutoff = 20.0000 Ry
charge density cutoff = 80.0000 Ry
scf convergence threshold = 1.0E-06
mixing beta = 0.3000
number of iterations used = 8 TF mixing
Exchange-correlation= SLA PW PBE PBE
( 1 4 3 4 0 0 0)
Effective Screening Medium Method
=================================
Boundary Conditions: Metal-Slab-Metal
total charge in unit cell = 0.0000
grid points for fit at edges = 4
>>>>> Grand-Canonical SCF is activated <<<<<
Initial Total Charge = 0.000000 e
Target Fermi Energy = -4.751000 eV
Thr. of Fermi Energy = 0.010000 eV
Wave-shift of Kerker = 0.400000 bohr^-1
Wave-shift of Hartree = 1.500000 bohr^-1
Mixing Rate of Fermi = 0.050000
celldm(1)= 10.822273 celldm(2)= 0.000000 celldm(3)= 0.000000
celldm(4)= 0.000000 celldm(5)= 0.000000 celldm(6)= 0.000000
crystal axes: (cart. coord. in units of alat)
a(1) = ( 1.000000 0.000000 0.000000 )
a(2) = ( 0.000000 1.000000 0.000000 )
a(3) = ( 0.000000 0.000000 2.095374 )
reciprocal axes: (cart. coord. in units 2 pi/alat)
b(1) = ( 1.000000 0.000000 0.000000 )
b(2) = ( 0.000000 1.000000 0.000000 )
b(3) = ( 0.000000 0.000000 0.477242 )
PseudoPot. # 1 for Al read from file:
/Users/otani/Program/q-e/git-worktrees/dev-rism/pseudo/Al.pbe-n-van.UPF
MD5 check sum: cbc97ad259b400557db688b98a6ada97
Pseudo is Ultrasoft + core correction, Zval = 3.0
Generated by new atomic code, or converted to UPF format
Using radial grid of 893 points, 2 beta functions with:
l(1) = 0
l(2) = 1
Q(r) pseudized with 8 coefficients, rinner = 0.900 0.900 0.900
atomic species valence mass pseudopotential
Al 3.00 26.98154 Al( 1.00)
16 Sym. Ops., with inversion, found
Cartesian axes
site n. atom positions (alat units)
1 Al tau( 1) = ( 0.0000000 0.0000000 0.0000000 )
2 Al tau( 2) = ( 0.5000000 0.0000000 0.0000000 )
3 Al tau( 3) = ( 0.0000000 0.5000000 0.0000000 )
4 Al tau( 4) = ( 0.5000000 0.5000000 0.0000000 )
number of k points= 6 Methfessel-Paxton smearing, width (Ry)= 0.0300
cart. coord. in units 2pi/alat
k( 1) = ( 0.0833333 0.0833333 0.0000000), wk = 0.2222222
k( 2) = ( 0.0833333 0.2500000 0.0000000), wk = 0.4444444
k( 3) = ( 0.0833333 0.4166667 0.0000000), wk = 0.4444444
k( 4) = ( 0.2500000 0.2500000 0.0000000), wk = 0.2222222
k( 5) = ( 0.2500000 0.4166667 0.0000000), wk = 0.4444444
k( 6) = ( 0.4166667 0.4166667 0.0000000), wk = 0.2222222
Dense grid: 32157 G-vectors FFT dimensions: ( 32, 32, 72)
Estimated max dynamical RAM per process > 9.36 MB
Estimated total dynamical RAM > 37.46 MB
Check: negative core charge= -0.000012
Initial potential from superposition of free atoms
starting charge 11.9901, renormalised to 12.0000
negative rho (up, down): 1.687E-04 0.000E+00
Starting wfcs are 16 randomized atomic wfcs
total cpu time spent up to now is 0.4 secs
Self-consistent Calculation
iteration # 1 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.00E-05, avg # of iterations = 17.8
negative rho (up, down): 9.000E-06 0.000E+00
total cpu time spent up to now is 0.8 secs
total energy = -49.53095199 Ry
estimated scf accuracy < 0.02371222 Ry
total charge of GC-SCF = -0.00480501 e
the Fermi energy = -5.16070019 eV
(error : 0.40970019 eV)
iteration # 2 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.00E-05, avg # of iterations = 2.3
total cpu time spent up to now is 0.9 secs
total energy = -49.51012486 Ry
estimated scf accuracy < 0.01287084 Ry
total charge of GC-SCF = -0.01399538 e
the Fermi energy = -4.96402357 eV
(error : 0.21302357 eV)
iteration # 3 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.00E-05, avg # of iterations = 7.0
total cpu time spent up to now is 1.0 secs
total energy = -49.51795785 Ry
estimated scf accuracy < 0.00025062 Ry
total charge of GC-SCF = -0.00275473 e
the Fermi energy = -4.42209081 eV
(error : 0.32890919 eV)
iteration # 4 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 2.09E-06, avg # of iterations = 3.5
total cpu time spent up to now is 1.1 secs
total energy = -49.51770110 Ry
estimated scf accuracy < 0.00019423 Ry
total charge of GC-SCF = 0.00519595 e
the Fermi energy = -4.56319049 eV
(error : 0.18780951 eV)
iteration # 5 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.62E-06, avg # of iterations = 3.7
total cpu time spent up to now is 1.2 secs
total energy = -49.51791954 Ry
estimated scf accuracy < 0.00001185 Ry
total charge of GC-SCF = 0.01432052 e
the Fermi energy = -4.55139812 eV
(error : 0.19960188 eV)
iteration # 6 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 9.89E-08, avg # of iterations = 10.8
total cpu time spent up to now is 1.4 secs
total energy = -49.51797749 Ry
estimated scf accuracy < 0.00000605 Ry
total charge of GC-SCF = 0.02331667 e
the Fermi energy = -4.58963607 eV
(error : 0.16136393 eV)
iteration # 7 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 5.06E-08, avg # of iterations = 12.7
total cpu time spent up to now is 1.5 secs
total energy = -49.51776598 Ry
estimated scf accuracy < 0.00000198 Ry
total charge of GC-SCF = 0.03903898 e
the Fermi energy = -4.63505465 eV
(error : 0.11594535 eV)
iteration # 8 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 1.66E-08, avg # of iterations = 7.2
total cpu time spent up to now is 1.7 secs
total energy = -49.51774452 Ry
estimated scf accuracy < 0.00000052 Ry
total charge of GC-SCF = 0.03903063 e
the Fermi energy = -4.72660777 eV
(error : 0.02439223 eV)
iteration # 9 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 4.35E-09, avg # of iterations = 8.8
total cpu time spent up to now is 1.9 secs
total energy = -49.51758127 Ry
estimated scf accuracy < 0.00000112 Ry
total charge of GC-SCF = 0.04264851 e
the Fermi energy = -4.73121792 eV
(error : 0.01978208 eV)
iteration # 10 ecut= 20.00 Ry beta= 0.30
Davidson diagonalization with overlap
ethr = 4.35E-09, avg # of iterations = 2.0
total cpu time spent up to now is 1.9 secs
End of self-consistent calculation
k = 0.0833 0.0833 0.0000 ( 3999 PWs) bands (ev):
-11.8429 -8.2675 -8.2675 -6.5594 -6.5594 -5.7742 -4.7823 -3.9105
-2.6144 -2.5442
k = 0.0833 0.2500 0.0000 ( 4011 PWs) bands (ev):
-11.5947 -9.4000 -8.0233 -6.3317 -5.8810 -5.5367 -4.9880 -4.4284
-3.4717 -2.3136
k = 0.0833 0.4167 0.0000 ( 4016 PWs) bands (ev):
-11.1005 -10.3651 -7.5377 -6.8180 -5.8803 -5.2245 -5.0646 -4.3664
-3.1533 -1.8558
k = 0.2500 0.2500 0.0000 ( 4007 PWs) bands (ev):
-11.3470 -9.1557 -9.1557 -7.0013 -5.2995 -4.7660 -4.7660 -3.4540
-3.2379 -3.2379
k = 0.2500 0.4167 0.0000 ( 4019 PWs) bands (ev):
-10.8534 -10.1191 -8.6693 -7.9473 -4.8282 -4.3361 -4.1310 -3.7540
-2.9538 -2.7726
k = 0.4167 0.4167 0.0000 ( 4005 PWs) bands (ev):
-10.3614 -9.6297 -9.6296 -8.9017 -4.3576 -3.6624 -3.6623 -2.9697
-2.6062 -2.6061
the Fermi energy is -4.7447 ev
! total energy = -49.51752846 Ry
estimated scf accuracy < 0.00000010 Ry
! total charge of GC-SCF = 0.04382689 e
smearing contrib. (-TS) = -0.00036920 Ry
internal energy E=F+TS = -49.51715927 Ry
The total energy is F=E-TS. E is the sum of the following terms:
one-electron contribution = -144.55438373 Ry
hartree contribution = 72.61561230 Ry
xc contribution = -39.20501529 Ry
ewald contribution = 61.64193145 Ry
pot.stat. contrib. (-muN) = -0.01530400 Ry
convergence has been achieved in 10 iterations
Forces acting on atoms (cartesian axes, Ry/au):
atom 1 type 1 force = 0.00000000 0.00000000 0.00000000
atom 2 type 1 force = 0.00000000 0.00000000 0.00000000
atom 3 type 1 force = 0.00000000 0.00000000 0.00000000
atom 4 type 1 force = 0.00000000 0.00000000 0.00000000
Total force = 0.000000 Total SCF correction = 0.000000
Writing all to output data dir /Users/otani/Program/q-e/git-worktrees/dev-rism/tempdir/Al001_bc2_GCSCF_vp05.save/
init_run : 0.40s CPU 0.41s WALL ( 1 calls)
electrons : 1.45s CPU 1.50s WALL ( 1 calls)
forces : 0.06s CPU 0.06s WALL ( 1 calls)
Called by init_run:
wfcinit : 0.03s CPU 0.03s WALL ( 1 calls)
potinit : 0.02s CPU 0.02s WALL ( 1 calls)
hinit0 : 0.30s CPU 0.30s WALL ( 1 calls)
Called by electrons:
c_bands : 1.18s CPU 1.21s WALL ( 10 calls)
sum_band : 0.13s CPU 0.14s WALL ( 10 calls)
v_of_rho : 0.10s CPU 0.10s WALL ( 11 calls)
newd : 0.03s CPU 0.03s WALL ( 11 calls)
mix_rho : 0.02s CPU 0.02s WALL ( 10 calls)
Called by c_bands:
init_us_2 : 0.02s CPU 0.02s WALL ( 132 calls)
init_us_2:cp : 0.02s CPU 0.02s WALL ( 132 calls)
cegterg : 1.16s CPU 1.18s WALL ( 63 calls)
Called by *egterg:
cdiaghg : 0.06s CPU 0.06s WALL ( 518 calls)
h_psi : 0.90s CPU 0.92s WALL ( 524 calls)
s_psi : 0.02s CPU 0.02s WALL ( 524 calls)
g_psi : 0.01s CPU 0.01s WALL ( 455 calls)
Called by h_psi:
h_psi:calbec : 0.04s CPU 0.04s WALL ( 524 calls)
vloc_psi : 0.83s CPU 0.84s WALL ( 524 calls)
add_vuspsi : 0.03s CPU 0.03s WALL ( 524 calls)
General routines
calbec : 0.05s CPU 0.05s WALL ( 608 calls)
fft : 0.15s CPU 0.15s WALL ( 132 calls)
ffts : 0.00s CPU 0.00s WALL ( 10 calls)
fftw : 0.76s CPU 0.78s WALL ( 7348 calls)
Parallel routines
PWSCF : 1.94s CPU 2.01s WALL
This run was terminated on: 11:19:49 1Dec2021
=------------------------------------------------------------------------------=
JOB DONE.
=------------------------------------------------------------------------------=